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Beilstein J. Org. Chem. 2010, 6, No. 79, doi:10.3762/bjoc.6.79
Graphical Abstract
Scheme 1: Synthesis of carbonitrile 1.
Scheme 2: Coupling of the β-DMCD-caged carbonitrile derivative 1-DMCD with PVAm to yield the fluorophore-func...
Figure 1: Solid state 13C-{1H}-CP-MAS NMR spectra of pure PVAm (a), functionalized PVAm 1-P (b) and the model...
Scheme 3: Synthesis of 1-Si by nucleophilic aromatic substitution of 1 adsorbed onto silica particles.
Figure 2: Wide-scan X-ray photoelectron spectra (left), C 1s and N 1s high-resolution spectra (right) of bare...
Figure 3: Pore-size distribution of bare silica, PVAm/silica and 1-Si.
Figure 4: UV–vis absorption and emission diffuse reflectance spectra of sample 1-Si.
Figure 5: Normalized absorption and emission spectra of 1-M (a) and 1-P (b).
Figure 6: Normalized emission spectra of 1-P in water at four different pH values and a sketch of the assumed...